资源类型

期刊论文 686

会议视频 40

会议专题 1

年份

2024 2

2023 135

2022 115

2021 83

2020 45

2019 48

2018 30

2017 34

2016 27

2015 30

2014 18

2013 18

2012 26

2011 26

2010 20

2009 13

2008 13

2007 17

2006 4

2005 1

展开 ︾

关键词

碳中和 24

能源 10

二氧化碳 6

低碳经济 6

环境 6

低碳发展 4

低碳 3

天然气 3

绿色化工 3

CCS 2

产业结构 2

光催化 2

力学性能 2

化学吸收 2

化石能源 2

协同效应 2

固体氧化物燃料电池 2

土地利用变化 2

碳基燃料 2

展开 ︾

检索范围：

排序： 展示方式：

Pore structure of cementitious material enhanced by graphitic nanomaterial: a critical review

S.A. GHAHARI, E. GHAFARI, L. ASSI

《结构与土木工程前沿（英文）》 2018年 第12卷 第1期   页码 137-147 doi: 10.1007/s11709-017-0431-9

摘要： Carbon nano tubes (CNT) has been introduced as an efficient nanomaterial in order to improve the mechanical and durability properties of concrete. The effect of CNT on the microstructures of cementitious materials has been widely reported. This paper combines a critical review on the effect of CNT on the pore and microstructure of cement composite with a discussion on the porosity measurement of pastes containing CNT using mercury intrusion porosimetry techniques (MIP). It was found that, surface treatment by H SO and HNO solution forms carboxyl acid groups on CNTs’ surfaces that lead to the improvement of reinforcement. In this scope, this review paper involves analyzing the effect of CNT on the microstructure and the pore structure of cementitious materials. The existing methods of measuring the porosity of cementitious material are reviewed, in particular, the contact angle measurement is discussed in detail in which the most effective parameters and possible errors of calculation is presented.

关键词： carbon nano tubes     microstructure     porosity     mercury intrusion porosimetry     cement composite    

HTML PDF 收藏

Pd nano-catalyst supported on biowaste-derived porous nanofibrous carbon microspheres for efficient catalysis

《化学科学与工程前沿（英文）》 2023年 第17卷 第9期   页码 1289-1300 doi: 10.1007/s11705-023-2299-7

摘要： Environmental pollution caused by the presence of aromatic aldehydes and dyes in wastewater is a serious global concern. An effective strategy for the removal of these pollutants is their catalytic conversion, possibly to valuable compounds. Therefore, the design of efficient, stable and long-lifetime catalysts is a worthwhile research goal. Herein, we used nanofibrous carbon microspheres (NCM) derived from the carbohydrate chitin present in seafood waste, and characterized by interconnected nanofibrous networks and N/O-containing groups, as carriers for the manufacture of a highly dispersed, efficient and stable Pd nano-catalyst (mean diameter ca. 2.52 nm). Importantly, the carbonised chitin’s graphitized structure, defect presence and large surface area could promote the transport of electrons between NCM and Pd, thereby endowing NCM supported Pd catalyst with high catalytic activity. The NCM supported Pd catalyst was employed in the degradation of some representative dyes and the chemoselective hydrogenation of aromatic aldehydes; this species exhibited excellent catalytic activity and stability, as well as applicability to a broad range of aromatic aldehydes, suggesting its potential use in green industrial catalysis.

关键词： biowaste chitin     nanofibrous     palladium     nano-catalyst     catalysis    

HTML PDF 收藏

Diversity-oriented synthesis of blue emissive nitrogen heterocycles and their conjugation with carbonnano-onions

Viviana Maffeis, Lisa Moni, Daniele Di Stefano, Silvia Giordani, Renata Riva

《化学科学与工程前沿（英文）》 2020年 第14卷 第1期   页码 76-89 doi: 10.1007/s11705-019-1833-0

摘要： The search for new fluorescent molecules for possible applications as functional -electron systems and their conjugation with different nanomaterials is nowadays of paramount importance to broaden the availability of materials with different properties. Herein we present a diversity-oriented approach to heterocyclic luminophores based on a multicomponent Ugi reaction followed by a Pd-mediated cascade sequence. The new molecules are coupled to carbon nano-onions, and hybrid systems represent the first example of blue emitters conjugated with these carbon nanoparticles.

关键词： carbon nano-onions     multicomponent reactions     blue emitters     fluorescence     isoquinolines    

HTML PDF 收藏

High-efficiency inspecting method for mobile robots based on task planning for heat transfer tubes in

《机械工程前沿（英文）》 2023年 第18卷 第2期 doi: 10.1007/s11465-022-0741-z

摘要： Many heat transfer tubes are distributed on the tube plates of a steam generator that requires periodic inspection by robots. Existing inspection robots are usually involved in issues: Robots with manipulators need complicated installation due to their fixed base; tube mobile robots suffer from low running efficiency because of their structural restricts. Since there are thousands of tubes to be checked, task planning is essential to guarantee the precise, orderly, and efficient inspection process. Most in-service robots check the task tubes using row-by-row and column-by-column planning. This leads to unnecessary inspections, resulting in a long shutdown and affecting the regular operation of a nuclear power plant. Therefore, this paper introduces the structure and control system of a dexterous robot and proposes a task planning method. This method proceeds into three steps: task allocation, base position search, and sequence planning. To allocate the task regions, this method calculates the tool work matrix and proposes a criterion to evaluate a sub-region. And then all tasks contained in the sub-region are considered globally to search the base positions. Lastly, we apply an improved ant colony algorithm for base sequence planning and determine the inspection orders according to the planned path. We validated the optimized algorithm by conducting task planning experiments using our robot on a tube sheet. The results show that the proposed method can accomplish full task coverage with few repetitive or redundant inspections and it increases the efficiency by 33.31% compared to the traditional planning algorithms.

关键词： steam generator transfer tubes     mobile robot     dexterous structure     task planning     efficient inspection    

HTML PDF 收藏

Theoretical study on the confine-stiffening effect and fractal cracking of square concrete filled steel tubes

《结构与土木工程前沿（英文）》 2021年 第15卷 第6期   页码 1317-1336 doi: 10.1007/s11709-021-0763-3

摘要： Tension stress in steel-concrete composite is widely observed in engineering design. Based on an experimental program on tension performance of three square concrete-filled tubes (SCFT), the tension theory of SCFT is proposed using a mechanics-based approach. The tension stiffening effect, the confining strengthening effect and the confining stiffening effect, observed in tests of SCFTs are included in the developed tension theory model. Subsequently, simplified constitutive models of steel and concrete are proposed for the axial tension performance of SCFT. Based on the MSC.MARC software, a special fiber beam-column element is proposed to include the confining effect of SCFTs under tension and verified. The proposed analytical theory, effective formulas, and equivalent constitutive laws are extensively verified against three available tests reported in the literature on both global level (e.g., load-displacement curves) and strain level. The experimental verification proves the accuracy of the proposed theory and formulations in simulating the performance of SCFT members under tension with the capability to accurately predict the tensile strength and stiffness enhancements and realistically simulate the fractal cracking phenomenon.

关键词： square concrete filled tubes     confine-stiffening     confine-strengthening     fractal cracking     fracture    

HTML PDF 收藏

Carbonized nano/microparticles for enhanced mechanical properties and electromagnetic interference shielding

Rao Arsalan KHUSHNOOD,Sajjad AHMAD,Luciana RESTUCCIA,Consuelo SPOTO,Pravin JAGDALE,Jean-Marc TULLIANI,Giuseppe Andrea FERRO

《结构与土木工程前沿（英文）》 2016年 第10卷 第2期   页码 209-213 doi: 10.1007/s11709-016-0330-5

摘要： In the present work, carbon nano/microparticles obtained by controlled pyrolysis of peanut (PS) and hazelnut (HS) shells are presented. These materials were characterized by Raman spectroscopy and field emission-scanning electron microscopy (FE-SEM). When added to cement paste, up to 1 wt%, these materials led to an increase of the cement matrix flexural strength and of toughness. Moreover, with respect to plain cement, the total increase in electromagnetic radiation shielding effect when adding 0.5 wt% of PS or HS in cement composites is much higher in comparison to the ones reported in the literature for CNTs used in the same content.

关键词： carbon nano/microparticles     green cement     toughness mechanism     electromagnetic shielding effect    

HTML PDF 收藏

Experimental and DFT insights into nitrogen and sulfur co-doped carbon nanotubes for effective desulfurization

《环境科学与工程前沿（英文）》 2021年 第15卷 第5期 doi: 10.1007/s11783-021-1397-3

摘要：

• Synthesis of NS-CNTS is used in a high desulfurization performance.

关键词： Dibenzothiophene (DBT)     Tertiary methyl mercaptan     Adsorption     Carbon nano tube (CNT)     Desulfurization     Doping    

HTML PDF 收藏

Modern developments related to nanotechnology and nanoengineering of concrete

Konstantin SOBOLEV

《结构与土木工程前沿（英文）》 2016年 第10卷 第2期   页码 131-141 doi: 10.1007/s11709-016-0343-0

摘要： This paper reports on modern developments related to nanotechnology of cement and concrete. Recent advances in instrumentation and design of advanced nano-composite materials is discussed. New technological directions and historical milestones in nanoengineering and nanomodi?cation of cement-based materials are presented. It is concluded that there is a strong potential of nanotechnology to improve the performance of cement-based materials.

关键词： nanotechnology     cement     concrete     nanoparticle     nano-composite     nanomodification     carbon nanotubes     C-S-H gel     photocatalyst    

HTML PDF 收藏

Civil and structural engineering applications, recent trends, research and developments on pultruded fiber reinforced polymer closed sections: a review

Alfred Kofi GAND, Tak-Ming CHAN, James Toby MOTTRAM

《结构与土木工程前沿（英文）》 2013年 第7卷 第3期   页码 227-244 doi: 10.1007/s11709-013-0216-8

摘要： The objectives of this study are to review and evaluate the developments and applications of pultruded fiber-reinforced polymer composites in civil and structural engineering and review advances in research and developments. Several case applications are reviewed. The paper presents a state-of-the-art review of fundamental research on the behavior of pultruded fiber reinforced polymer closed sections and highlights gaps in knowledge and areas of potential further research.

关键词： fibre reinforced polymer composites     behaviour of FRPs tubular sections     pultruded FRP tubular profiles     FRP tubes in bridges     applications of pultruded FRP tubes     new-build with FRP tubes    

HTML PDF 收藏

Pyrolysis transformation of ZIF-8 wrapped with polytriazine to nitrogen enriched core-shell polyhedrons carbon

Nuoya Wang, Xinhua Huang, Lei Zhang, Jinsong Hu, Yimin Chao, Ruikun Zhao

《化学科学与工程前沿（英文）》 2021年 第15卷 第4期   页码 944-953 doi: 10.1007/s11705-020-2005-y

摘要： This work presents a simple effective strategy to synthesize -doped and shell-controlled carbon nanocages through a package baking approach. A green approach to synthesize core-shell ZIF-8@PTZ nanoparticles involves zinc contained ZIF-8 core wrapped by a N-enriched polytriazine (PTZ). Synthesized core-shell ZIF-8@PTZ nanoparticles are calcinated to further sublime zinc through PTZ shell and washed by HCl, leaving a porous carbon structure. At the meantime, hollow cavities were introduced into N-doped carbon polyhedrons via the sacrifice of ZIF-8 template (noted as ZIF-8@C/N-x). The electrochemical performance of the ZIF-8@C/N-x as supercapacitor electrode has demonstrated high energy density and specific capacitance, as well as a long-term cycleability showing 92% capacitance retention after 10000 cycles. There is a systematic correlation between micro-/meso-porosity of ZIF-8@C/N-x and their electrochemical performances.

关键词： core-shell     EDLC electrode     microporos nano polygons     nitrogen doped carbon    

HTML PDF 收藏

New technique of precision necking for long tubes with variable wall thickness

Yongqiang GUO, Chunguo XU, Jingtao HAN, Zhengyu WANG

《机械工程前沿（英文）》 2020年 第15卷 第4期   页码 622-630 doi: 10.1007/s11465-019-0565-7

摘要： This study analyzed the deformation law of rear axles with variable wall thickness under bidirectional horizontal extrusion and found that necking was accompanied by upsetting deformation through theoretical calculation, numerical simulation, and experimental research. The sequence and occurrence of necking and upsetting deformations were obtained. A theory of deformation was proposed by controlling the distribution of temperature field. Effective processes to control the wall thickness of rear axle at different positions were also proposed. The ultimate limit deformation with a necking coefficient of 0.68 could be achieved using the temperature gradient coefficient. A new technology of two-step heating and two-step extrusion for a 13 t rear axle was developed, qualified test samples were obtained, and suggestions for further industrial application were put forward.

关键词： extrusion     rear axle     necking coefficient     temperature gradient    

HTML PDF 收藏

Water-dispersible nano-pollutions reshape microbial metabolism in type-specific manners: A metabolic

《环境科学与工程前沿（英文）》 2022年 第16卷 第9期 doi: 10.1007/s11783-022-1548-1

摘要：

• Water-dispersible nano-pollutions exhibit type-specific toxic effects on E. coli.

关键词： Nano-toxicity     Nano-plastics     Quantum dots     Microbial metabolite     Metabolic dysregulation    

HTML PDF 收藏

Laboratory investigation of emulsified asphalt binder modified with wood-derived nano-cellulose and nano

Yunge WEI; Jiayu WANG; Ruoyu LI; Ling XU; Feipeng XIAO

《结构与土木工程前沿（英文）》 2022年 第16卷 第11期   页码 1474-1485 doi: 10.1007/s11709-022-0869-2

摘要： Emulsified asphalt is the primary material for preventive maintenance and cold-mix paving, but its low cohesive strength and poor mechanical properties limit its wide application, even with polymer modification. In this study, Styrene-Butadiene Rubber (SBR) emulsified asphalt was modified with nano-cellulose materials, namely nano paper-cellulose (NPC) and wood-derived nano-cellulose (WDC), to improve its properties. A novel preparation method of nano-cellulose solution was developed, including blending, ultrasonic stirring, and centrifugal treatment. Four types of nano-cellulose solution (0.5% NPC, 0.5%, 1.0%, and 1.5% WDC by weight of water) were selected. The microscopy analysis indicated that 0.5% WDC emulsion had a smaller particle size than 1.5% WDC emulsion. The rheology test indicated that WDC modified residue improved rutting resistance with the increased solution dosage due to the cross-linking effect, but its creep-and-recovery performance was worse than that of SBR emulsion residue. The NPC modified binder had a higher rutting factor than WDC modified binder at the same dosage after short-term aging. In addition, 1.0% WDC could be regarded as the optimal dosage in terms of fatigue and low-temperature performance. Furthermore, Fourier Transform Infrared Spectroscopy (FTIR) results showed that 0.5% NPC modified residue performed better in long-term aging resistance compared with 0.5%WDC modified asphalt.

关键词： nano-cellulose     emulsified asphalt binder     dispersion     rheological properties     Fourier transform infrared spectroscopy    

HTML PDF 收藏

Effects of different types of biochar on the properties and reactivity of nano zero-valent iron in soil

《环境科学与工程前沿（英文）》 2021年 第15卷 第5期 doi: 10.1007/s11783-021-1388-4

摘要：

• Biochar enhanced the mobility and stability of zero-valent iron nanoparticles.

关键词： Nano zero-valent iron     Biochar     BDE209     Transport     Soil    

HTML PDF 收藏

Immunological effects of nano-enabled hyperthermia for solid tumors: opportunity and challenge

《化学科学与工程前沿（英文）》 2022年 第16卷 第3期   页码 333-344 doi: 10.1007/s11705-021-2059-5

摘要： Compared to conventional hyperthermia that is limited by low selectivity and severe side effects, nano-enabled hyperthermia yields great potentials to tackle these limitations for cancer treatment. Another major advance is the observation of immunological responses associated with nano-enabled hyperthermia, which introduces a new avenue, allowing a potential paradigm shift from the acutely effective and cytotoxicity-centric response to the next-phase discovery, i.e., long-lasting and/or systemic anti-tumor immunity. This perspective first discusses the temperature-gradient and the spatially-structured immunological landscape in solid tumors receiving nano-enabled hyperthermia. This includes the discussion about underlying mechanism such as immunogenic cell death, which initiates a profound immunological chain reaction. In order to propagate the immune activation as a viable therapeutic principle, we further discussed the tumor type-specific complexity in the immunological tumor microenvironment, including the creative design of nano-enabled combination therapy to synergize with nano-enabled hyperthermia.

关键词： nano-enabled hyperthermia     immunogenic cell death     heterogeneous immunological landscape     tumor microenvironment    

HTML PDF 收藏

标题 作者 时间 类型 操作

Pore structure of cementitious material enhanced by graphitic nanomaterial: a critical review

S.A. GHAHARI, E. GHAFARI, L. ASSI

期刊论文

Pd nano-catalyst supported on biowaste-derived porous nanofibrous carbon microspheres for efficient catalysis

期刊论文

Diversity-oriented synthesis of blue emissive nitrogen heterocycles and their conjugation with carbonnano-onions

Viviana Maffeis, Lisa Moni, Daniele Di Stefano, Silvia Giordani, Renata Riva

期刊论文

High-efficiency inspecting method for mobile robots based on task planning for heat transfer tubes in

期刊论文

Theoretical study on the confine-stiffening effect and fractal cracking of square concrete filled steel tubes

期刊论文

Carbonized nano/microparticles for enhanced mechanical properties and electromagnetic interference shielding

Rao Arsalan KHUSHNOOD,Sajjad AHMAD,Luciana RESTUCCIA,Consuelo SPOTO,Pravin JAGDALE,Jean-Marc TULLIANI,Giuseppe Andrea FERRO

期刊论文

Experimental and DFT insights into nitrogen and sulfur co-doped carbon nanotubes for effective desulfurization

期刊论文

Modern developments related to nanotechnology and nanoengineering of concrete

Konstantin SOBOLEV

期刊论文

Civil and structural engineering applications, recent trends, research and developments on pultruded fiber reinforced polymer closed sections: a review

Alfred Kofi GAND, Tak-Ming CHAN, James Toby MOTTRAM

期刊论文

Pyrolysis transformation of ZIF-8 wrapped with polytriazine to nitrogen enriched core-shell polyhedrons carbon

Nuoya Wang, Xinhua Huang, Lei Zhang, Jinsong Hu, Yimin Chao, Ruikun Zhao

期刊论文

New technique of precision necking for long tubes with variable wall thickness

Yongqiang GUO, Chunguo XU, Jingtao HAN, Zhengyu WANG

期刊论文

Water-dispersible nano-pollutions reshape microbial metabolism in type-specific manners: A metabolic

期刊论文

Laboratory investigation of emulsified asphalt binder modified with wood-derived nano-cellulose and nano

Yunge WEI; Jiayu WANG; Ruoyu LI; Ling XU; Feipeng XIAO

期刊论文

Effects of different types of biochar on the properties and reactivity of nano zero-valent iron in soil

期刊论文

Immunological effects of nano-enabled hyperthermia for solid tumors: opportunity and challenge

期刊论文